|The Universe of Discourse|
12 recent entries
Fri, 07 Dec 2007
Freshman electromagnetism questions
But, as I keep saying here, I do not understand physics very well, and I don't know much about it. And every time I go to a freshman physics lecture I come out feeling like I understand it less than I went in.
I've started writing down my questions in class, even though I don't really have anyone to ask them to. (I don't want to take up the professor's time, since she presumably has her hands full taking care of the paying customers.) When I ask people I know who claim to understand physics, they usually can't give me plausible answers.
Maybe I should mutter something here under my breath about how mathematicians and mathematics students are expected to have a better grasp on fundamental matters.
The last time this came up for me I was trying to understand the phenomenon of dissolving. Specifically, why does it usually happen that substances usually dissolve faster and more thoroughly in warmer solutions than in cooler solutions? I asked a whole bunch of people about this, up to and including a full professor of physical chemistry, and never got a decent answer.
The most common answer, in fact, was incredibly crappy: "the warm solution has higher entropy". This is a virtus dormitiva if ever there was one. There's a scene in a play by Molière in which a candidate for a medical degree is asked by the examiners why opium puts people to sleep. His answer, which is applauded by the examiners, is that it puts people to sleep because it has a virtus dormitiva. That is, a sleep-producing power. Saying that warm solutions dissolve things better than cold ones because they have more entropy is not much better than saying that it is because they have a virtus dormitiva.
The entropy is not a real thing; it is a reification of the power that warmer substances have to (among other things) dissolve solutes more effectively than cooler ones. Whether you ascribe a higher entropy to the the warm solution, or a virtus dissolva to it, comes to the same thing, and explains nothing. I was somewhat disgusted that I kept getting this non-answer. (See my explanation of why we put salt on sidewalks when it snows to see what sort of answer I would have preferred. Probably there is some equally useless answer one could have given to that question in terms of entropy.)
(I have similar concerns about the notion of energy itself, which is central to physics, and yet seems to me to be another example of a false reification. There are dozens of apparently unrelated physical phenomena, which we throw into the same bin and call "energy". There are positions in gravitational and electric fields, linear motion, mass, rotation, heat, amplitude of waves, and so on, and all of these things seem to be interconvertible, more or less, and certain quantities of each can be converted into certain quantities of the others. But is there really any such thing as just plain energy, apart from its imagined association with these real phenomena? I think perhaps not. So energy is a very useful convenience in calculation, and I have no objection to it on that ground, but that does not mean that it is a real thing. Getting rid of it might lead to a clearer understanding of the phenomena it was intended to describe.
(Perhaps my position will seem less crackpottish if I a make an analogy with the concept of "center of gravity". In mechanics, many physical properties can be most easily understood in terms of the center of gravity of some object. For example, the gravitational effect of small objects far apart from one another can be conveniently approximated by supposing that all the mass of each object is concentrated at its center of gravity. A force on an object can be conveniently treated mathematically as a component acting toward the center of gravity, which tends to change the object's linear velocity, and a component acting perpendicular to that, which tends to change its angular velocity. But nobody ever makes the mistake of supposing that the center of gravity has any objective reality in the physical universe. Everyone understands that it is merely a mathematical fiction. I am considering the possibility that energy should be understood to be a mathematical fiction in the same sort of way. From the little I know about physics and physicists, it seems to me that physicists do not think of energy in this way. But I am really not sure.)
Anyway, none of this philosophizing is what I was hoping to discuss in this article. Today I wrote up some of the questions I jotted down in freshman physics class.
[ Addendum 20090204: I eventually remembered that Noether's theorem has something to say about the necessity of the energy concept. ]